| Type of Material: | Thesis |
| Title: | Design synthesis and scope of organocatalytic Azide Carbony 1 3 2 Cycloadditions |
| Researcher: | Surendra Reddy, Gundam. |
| Guide: | Ramachary, D.B |
| Department: | School of Chemistry |
| Publisher: | University of Hyderabad, Hyderabad |
| Place: | Hyderabad |
| Year: | 2020 |
| Language: | English |
| Subject: | Chemistry | Chemistry Applied | Physical Sciences | Physical and Basic Sciences |
| Dissertation/Thesis Note: | PhD; School of Chemistry, University of Hyderabad, Hyderabad, Hyderabad |
| Fulltext: | Shodhganga |
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| 005 | 2023-07-21 15:50:26 | |
| 008 | __ | 230721t2020||||ii#||||g|m||||||||||eng|| |
| 035 | __ | |a(IN-AhILN)th_448516 |
| 040 | __ | |aHYDR_500046|dIN-AhILN |
| 041 | __ | |aeng |
| 100 | __ | |aSurendra Reddy, Gundam.|eResearcher |
| 110 | __ | |aSchool of Chemistry|bUniversity of Hyderabad, Hyderabad|dHyderabad|ein |
| 245 | __ | |aDesign synthesis and scope of organocatalytic Azide Carbony 1 3 2 Cycloadditions |
| 260 | __ | |aHyderabad|bUniversity of Hyderabad, Hyderabad|c2020 |
| 300 | __ | |a210p|dNone |
| 502 | __ | |bPhD|cSchool of Chemistry, University of Hyderabad, Hyderabad, Hyderabad |
| 518 | __ | |oDate of Award|d2020 |
| 518 | __ | |oDate of Registration|d2014 |
| 520 | __ | |aFor the first time, an enolate-mediated organocatalytic vinyl azide-carbonyl [3+2]-cycloaddition (OrgVACC) of various ketones/aldehydes with vinyl azides is reported. It is an efficient intermolecular reaction with excellent outcomes with reference to rate, yield, selectivity, operational simplicity, substrate scope, catalyst simplicity, and vast applications. In the second chapter, for the first time, an enolate-mediated organocatalytic fluorogenic formal [3+2]-cycloaddition of (E)-1,4-diarylbut-3-en-1-ones and aryl azides is reported. The mild metal-free catalytic conditions of this reaction allowed us to synthesize a library of pure fluorescent coumarin-triazole dyes. It is an efficient formal [3+2]-cycloaddition for the synthesis of fully decorated C-vinyl-1,2,3-triazoles with excellent outcomes with reference to the rate, yield, selectivity, operation simplicity, substrate scope, and photophysical applications.newlineIn the third chapter, we demonstrated the metal-free regioselective synthesis of highl |
| 650 | __ | |aPhysical and Basic Sciences|2AIU |
| 653 | __ | |aChemistry |
| 653 | __ | |aChemistry Applied |
| 653 | __ | |aPhysical Sciences |
| 700 | __ | |aRamachary, D.B|eGuide |
| 856 | __ | |uhttp://shodhganga.inflibnet.ac.in/handle/10603/411867|yShodhganga |
| 905 | __ | |afromsg |
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