| Type of Material: | Thesis |
| Title: | Cyclization Cycloaddition reactions of nitriles Allenes and active methylene compounds |
| Researcher: | Kalyani, A |
| Guide: | Kumara Swamy, K.C |
| Department: | School of Chemistry |
| Publisher: | University of Hyderabad, Hyderabad |
| Place: | Hyderabad |
| Year: | 2022 |
| Language: | English |
| Subject: | Chemistry | Chemistry Applied | Physical Sciences | Physical and Basic Sciences |
| Dissertation/Thesis Note: | PhD; School of Chemistry, University of Hyderabad, Hyderabad, Hyderabad |
| Fulltext: | Shodhganga |
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| 001 | 448511 | |
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| 008 | __ | 230721t2022||||ii#||||g|m||||||||||eng|| |
| 035 | __ | |a(IN-AhILN)th_448511 |
| 040 | __ | |aHYDR_500046|dIN-AhILN |
| 041 | __ | |aeng |
| 100 | __ | |aKalyani, A|eResearcher |
| 110 | __ | |aSchool of Chemistry|bUniversity of Hyderabad, Hyderabad|dHyderabad|ein |
| 245 | __ | |aCyclization Cycloaddition reactions of nitriles Allenes and active methylene compounds |
| 260 | __ | |aHyderabad|bUniversity of Hyderabad, Hyderabad|c2022 |
| 300 | __ | |a169p|dNone |
| 502 | __ | |bPhD|cSchool of Chemistry, University of Hyderabad, Hyderabad, Hyderabad |
| 518 | __ | |oDate of Award|d2022 |
| 518 | __ | |oDate of Registration|d2015 |
| 520 | __ | |aThis thesis is divided into two parts: Part-A and Part-B. Part-A deals with the following topics: (i) Palladium catalyzed nitrile insertion followed by cyclization into 2,3and#8242;-biindole to yield indole fused and#945;-carboline scaffolds and cyanation of biindoles, (ii) Cyclization and cycloaddition reactions of phosphorus based allenes in the presence of [Pd]-catalyst to yield Pd-incorporated metal complexes and P-containing naphthalenes respectively, and (iii) Phosphine catalyzed cycloaddition of allenes with enynones followed by gold catalyzed intramolecular cyclization to yield furan fused polycycles. Overall, this part deals with the chemistry of compounds involving an sp-hybridized carbon (e.g., nitrile, allene, enynone). Part-B deals with Cu(I)-catalyzed ligand-free tandem one pot or sequential annulation via Knoevenagel intermediate that affords multifunctional naphthalenes, phenanthrenes, quinolines and benzo[b]carbazoles.newlineEach part is subdivided into three chapters: (a) Introduction (lit |
| 650 | __ | |aPhysical and Basic Sciences|2AIU |
| 653 | __ | |aChemistry |
| 653 | __ | |aChemistry Applied |
| 653 | __ | |aPhysical Sciences |
| 700 | __ | |aKumara Swamy, K.C|eGuide |
| 856 | __ | |uhttp://shodhganga.inflibnet.ac.in/handle/10603/411355|yShodhganga |
| 905 | __ | |afromsg |
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