| Type of Material: | Thesis |
| Title: | Studies on the reactive organotitanium intermediates and chiral 1,1′-Binaphthyl-2,2′-diamine derivatives |
| Researcher: | Ganesan, Selva |
| Guide: | Periasamy, M |
| Department: | School of Chemistry |
| Publisher: | University of Hyderabad, Hyderabad |
| Place: | Hyderabad |
| Year: | June, 2009 |
| Language: | English |
| Subject: | Reactive Organotitanium Intermediates | Chemistry | Physical and Basic Sciences |
| Dissertation/Thesis Note: | PhD |
| Fulltext: | Shodhganga |
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| 040 | __ | |aHYDR_500046|dIN-AhILN |
| 041 | __ | |aeng |
| 100 | __ | |aGanesan, Selva|eResearcher |
| 110 | __ | |aSchool of Chemistry|bUniversity of Hyderabad, Hyderabad|dHyderabad|ein |
| 245 | __ | |aStudies on the reactive organotitanium intermediates and chiral 1,1′-Binaphthyl-2,2′-diamine derivatives |
| 260 | __ | |aHyderabad|bUniversity of Hyderabad, Hyderabad|cJune, 2009 |
| 300 | __ | |c-|dNone|a189p. |
| 500 | __ | |aAppendix p.165-189, References Chapters wise given |
| 502 | __ | |bPhD |
| 518 | __ | |oDate of Award|d 2009 |
| 518 | __ | |oDate of Registration|d n.d. |
| 520 | __ | |aThis thesis entitled ?Studies on the Reactive Organotitanium Intermediates and Chiral 1,1and#8242;-Binaphthyl-2,2and#8242;-Diamine Derivatives? comprises of two parts. Each part is subdivided into two chapters under four sections namely Introduction, Results and Discussion, Conclusions and Experimental Section along with References. The work described in this thesis is exploratory in nature and the chapters are arranged in the order the investigations were executed. In Part I, investigations on the titanium reagents are described. Results of studies on the use of the TiCl4/Et3N reagent system for the preparation of chiral enolates for use in Mannich-type reaction are described in Chapter 1. The reaction of L-(-)-menthyl butyrate 1 and imines 2a-g with the TiCl4/Et3N reagent system gave the corresponding syn-and#946;-amino esters 3-9 in moderate to good yields with good selectivity (Scheme 1). The major amino ester products 3a and 9a were characterized by the single crystal X-ray analysis of the correspondin |
| 650 | __ | |aPhysical and Basic Sciences|2AIU |
| 653 | __ | |aReactive Organotitanium Intermediates |
| 653 | __ | |aChemistry |
| 700 | __ | |aPeriasamy, M|eGuide |
| 856 | __ | |uhttp://shodhganga.inflibnet.ac.in/handle/10603/4213|yShodhganga |
| 905 | __ | |afromsg |
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