Title : New reactive iron carbonyl reagents for applications in organic synthesis

Type of Material: Thesis
Title: New reactive iron carbonyl reagents for applications in organic synthesis
Researcher: Rameshkumar, C.
Guide: Periasamy, M.
Department: School of Chemistry
Publisher: University of Hyderabad, Hyderabad
Place: Hyderabad
Year: 24/04/2000
Language: English
Subject: Organic synthesis
Dissertation/Thesis Note: PhD
Fulltext: Shodhganga

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035__|a(IN-AhILN)th_447282
040__|aHYDR_500046|dIN-AhILN
041__|aeng
100__|aRameshkumar, C.|eResearcher
110__|aSchool of Chemistry|bUniversity of Hyderabad, Hyderabad|dHyderabad|ein
245__|aNew reactive iron carbonyl reagents for applications in organic synthesis
260__|aHyderabad|bUniversity of Hyderabad, Hyderabad|c24/04/2000
300__|avi, 176p.|dDVD
500__|aRepresentative spectra p.164-175
502__|bPhD
520__|aThis thesis describes studies on the "New Reactive Iron Carbonyl Reagents for Applications in Organic Synthesis". It comprises of three chapters. Each chapter is subdivided into four parts, namely Introduction, Results and Discussion, Conclusions and Experimental Section along with References. The work described in this thesis is exploratory in nature and the chapters are arranged in the order the investigations were executed. The first chapter describes the investigations on the reactions of alkynes with iron carbonyl species, prepared in situ using Fe(CO)5/NaBH4/CH3COOH and Fe3(CO)12/amine systems. In the introductory section, a brief review on the methods of preparation and synthetic applications of the readily accessible Fe(CO)5, Fe2(CO)9, Fe3(CO)12, Na2Fe(CO)4, HFe(CO)4 HFe2(CO)8 [HFe3(CO)u] H2Fe(CO)4, H2Fe3(CO)n and the coordinatively unsaturated iron carbonyl species such as "Fe(CO)4", and "Fe2(CO)8" are presented. Previously, it was observed in this laboratory that the reactive iron carbonyl specie
653__|aOrganic synthesis
700__|aPeriasamy, M.|eGuide
856__|uhttp://shodhganga.inflibnet.ac.in/handle/10603/1922|yShodhganga
905__|afromsg

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