Title : Development of organic synthetic methods using cobalt carbony reagents

Type of Material: Thesis
Title: Development of organic synthetic methods using cobalt carbony reagents
Researcher: Rajesh, T
Guide: Periasamy, M
Department: School of Chemistry
Publisher: University of Hyderabad, Hyderabad
Place: Hyderabad
Year: 23-09-98
Language: English
Subject: Organic synthetic
Dissertation/Thesis Note: PhD
Fulltext: Shodhganga

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035__|a(IN-AhILN)th_447270
040__|aHYDR_500046|dIN-AhILN
041__|aeng
100__|aRajesh, T|eResearcher
110__|aSchool of Chemistry|bUniversity of Hyderabad, Hyderabad|dHyderabad|ein
245__|aDevelopment of organic synthetic methods using cobalt carbony reagents
260__|aHyderabad|bUniversity of Hyderabad, Hyderabad|c23-09-98
300__|av 115p.|dDVD
500__|aReferences p.126-147
502__|bPhD
520__|aThis thesis deals with the results of the investigations carried out on the quotDevelopment of Organic Synthetic Methods Using Cobalt Carbonyl Reagents.quot It comprises of three chapters. Each chapter is subdivided into three parts. quotIntroduction,quot quotResults and Discussionquot and quotExperimental sectionquot along with references. The work described in this thesis is exploratory in nature and the chapters are arranged in the order the investigations were executed. Chapter 1 describes the preparation of alkyne-Co2(CO)6 complexes via reduction of CoBr2 with Zn in the presence of CO in CH2CI2/t-BuOH or toluene/t-BuOH for applications in Pauson-Khand cyclopentenone synthesis (Scheme 1). Recent developments in the Pauson-Khand reaction are briefly reviewed in the Introductory section. To facilitate the discussion, methods of preparation of (alkyne)Co2(CO)6 complexes are also briefly reviewed. Scheme 1 It has been observed tha. the amines/amides promote the Pauson-Khand reaction (alkyne)Co2(CO)6 complex
653__|aOrganic synthetic
700__|aPeriasamy, M|eGuide
856__|uhttp://shodhganga.inflibnet.ac.in/handle/10603/1864|yShodhganga
905__|afromsg

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