Type of Material: | Thesis |
Title: | Development of organic synthetic methods using cobalt carbony reagents |
Researcher: | Rajesh, T |
Guide: | Periasamy, M |
Department: | School of Chemistry |
Publisher: | University of Hyderabad, Hyderabad |
Place: | Hyderabad |
Year: | 23-09-98 |
Language: | English |
Subject: | Organic synthetic |
Dissertation/Thesis Note: | PhD |
Fulltext: | Shodhganga |
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001 | 447270 | |
003 | IN-AhILN | |
005 | 2023-07-06 15:27:44 | |
008 | __ | 230706t1970||||ii#||||g|m||||||||||eng|| |
035 | __ | |a(IN-AhILN)th_447270 |
040 | __ | |aHYDR_500046|dIN-AhILN |
041 | __ | |aeng |
100 | __ | |aRajesh, T|eResearcher |
110 | __ | |aSchool of Chemistry|bUniversity of Hyderabad, Hyderabad|dHyderabad|ein |
245 | __ | |aDevelopment of organic synthetic methods using cobalt carbony reagents |
260 | __ | |aHyderabad|bUniversity of Hyderabad, Hyderabad|c23-09-98 |
300 | __ | |av 115p.|dDVD |
500 | __ | |aReferences p.126-147 |
502 | __ | |bPhD |
520 | __ | |aThis thesis deals with the results of the investigations carried out on the quotDevelopment of Organic Synthetic Methods Using Cobalt Carbonyl Reagents.quot It comprises of three chapters. Each chapter is subdivided into three parts. quotIntroduction,quot quotResults and Discussionquot and quotExperimental sectionquot along with references. The work described in this thesis is exploratory in nature and the chapters are arranged in the order the investigations were executed. Chapter 1 describes the preparation of alkyne-Co2(CO)6 complexes via reduction of CoBr2 with Zn in the presence of CO in CH2CI2/t-BuOH or toluene/t-BuOH for applications in Pauson-Khand cyclopentenone synthesis (Scheme 1). Recent developments in the Pauson-Khand reaction are briefly reviewed in the Introductory section. To facilitate the discussion, methods of preparation of (alkyne)Co2(CO)6 complexes are also briefly reviewed. Scheme 1 It has been observed tha. the amines/amides promote the Pauson-Khand reaction (alkyne)Co2(CO)6 complex |
653 | __ | |aOrganic synthetic |
700 | __ | |aPeriasamy, M|eGuide |
856 | __ | |uhttp://shodhganga.inflibnet.ac.in/handle/10603/1864|yShodhganga |
905 | __ | |afromsg |
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