| Type of Material: | Thesis |
| Title: | Synthesis and Catalytic studies of chiral -4- (2-Hydroxy-2, 2- Diarylethyl) – 2, 2- Dimethyl - Tetra aryl – 1,3 – Dioxolane 4, 5 – Dimethanols |
| Researcher: | Thomas, Beena |
| Guide: | Saud, I Ibnu |
| Publisher: | Mahatma Gandhi University, Kottayam |
| Place: | Kottayam |
| Year: | 2013-01-24 |
| Language: | English |
| Subject: | Chiral organic compounds | diastereomeric relationship | Chemical science | Chemical Engineering | Physical and Basic Sciences |
| Dissertation/Thesis Note: | PhD |
| Fulltext: | Shodhganga |
| 000 | 00000ctm a2200000ua 4500 | |
| 001 | 277702 | |
| 003 | IN-AhILN | |
| 005 | 2024-09-11 14:26:04 | |
| 008 | __ | 180814t2013||||ii#||||g|m||||||||||eng|| |
| 035 | __ | |a(IN-AhILN)th_277702 |
| 040 | __ | |aMGND_686560|dIN-AhILN |
| 041 | __ | |aeng |
| 100 | __ | |aThomas, Beena|eResearcher |
| 110 | __ | |ein |
| 245 | __ | |aSynthesis and Catalytic studies of chiral -4- (2-Hydroxy-2, 2- Diarylethyl) – 2, 2- Dimethyl - Tetra aryl – 1,3 – Dioxolane 4, 5 – Dimethanols |
| 260 | __ | |aKottayam|bMahatma Gandhi University, Kottayam|c2013-01-24 |
| 502 | __ | |bPhD |
| 520 | __ | |aA thorough structural analysis has been carried out to reveal thediastereomeric relationship between (2S,3S) and (2S,3R)-Tetrahydro-3-hydroxy-5-0x0-2,3-furandicarboxylic acids based on 'H NMR, NMR andHMBC (2D) spectral data. (ZS,3S)-Tetrahydr0-3-hydroxy-5-0~0-2,3-furandicarboxylic acid has been effectively used as starting point for thesynthesis of enantiomerically pure (4S,5S)4-(2-hydroxy-2,2-diarylethyl)-2,2-dimethyl-a,a,a',a'-tetraaryl-1,3-dioxolane-4,5-dimethanols which have beenfound to be promising chiral ligands for catalflc asymmetric Diels-Alderreaction. Various synthetic strategies were attempted starting from (2S,3S)-Tetrahydro-3-hydroxy-5-oxo-2,3-furandicarbolic acid to prepare potentialchiral molecules. |
| 650 | __ | |aChemical Engineering|2UGC |
| 650 | __ | |aPhysical and Basic Sciences|2AIU |
| 653 | __ | |aChiral organic compounds |
| 653 | __ | |adiastereomeric relationship |
| 653 | __ | |aChemical science |
| 700 | __ | |aSaud, I Ibnu|eGuide |
| 856 | __ | |uhttp://shodhganga.inflibnet.ac.in/handle/10603/6734|yShodhganga |
| 905 | __ | |anotification |
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